Requirements for the carbonation resistance of concrete mixes (AGB2008/012)
Overview
Background & policy context:
In Switzerland as well as in the rest of Europe the cement market is changing rapidly. These changes began in the middle of the 1990’s when in Switzerland the cement CEM II/A-LL (Portland-limestone cement) was launched. This cement has increasingly replaced the ordinary Portland cement CEM I. In the last few years a series of other cement types have been brought on the market. This trend runs parallel to the rest of Europe, with some country-specific differences.
Up to now it could be assumed, that with the use of the existing cements for new constructions the carbonation of concrete did not represent a direct and relevant risk for rebar corrosion any longer, since the actual standards (codes) for concrete constructions required a far higher concrete cover than earlier. With the expected new cement types this situation might change considerably. Thus, the innovations of the cement producers might imply certain risks for the durability of concrete constructions. It has to be considered in this context that critical chloride content for corrosion decreases with a decreasing pH of the pore water and, therefore, with the advancing carbonation of the concrete cover as well as.
With this project the influence of the concrete composition (cement type and content, w/c ratio) and the curing conditions on the carbonation resistance should be investigated. For this purpose the carbonation coefficient (mass for the carbonation resistance) of a variety of concrete compositions should be determined and correlated with physical and chemical parameters of the mixes.
Objectives:
The following goals should be achieved in the framework of this project:
- Definition of the requirements for the carbonation resistance of concrete mixes of the ASTRA (standard specifications of concrete mixes for civil and underground constructions) with new cement types and for the curing (performance-related design methods for concrete, possibly in dependence on the concrete cover and on the durability class acc. to SIA-Merkblatt 20029).
- Development of a proposal for a Swiss standard for a accelerated test methods of the carbonation resistance of concrete mixes (durability test, quality control).
Methodology:
Following steps are planned in the project:
- Production of concretes with different compositions in the laboratory
- Determination of different characteristic values for density (water conductivity, pore characteristics and gas permeability)
- Determination of the Na + -, K + - and Ca (OH) 2 content
- Determination of resistance to carbonation, depending on the preliminary storage and the CO2 content in the carbonation
- Correlation between carbonation with the sealing properties and the composition of the concrete (cement, cement content and w / c ratio and Na + - K + - and Ca (OH) 2 content).
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